New research could lead to more efficient electrical energy storage
Lawrence Livermore researchers have identified electrical charge-induced changes in the structure and bonding of graphitic carbon electrodes that may one day affect the way energy is stored.
The research could lead to an improvement in the capacity and efficiency of electrical energy storage systems, such as batteries and supercapacitors, needed to meet the burgeoning demands of consumer, industrial and green technologies.
Future technology requires energy storage systems to have much larger storage capability, rapid charge/discharge cycling and improved endurance. Progress in these areas demands a more complete understanding of energy storage processes from atomic through micron-length scales. Because these complex processes can change significantly as the system is charged and discharged, researchers have increasingly focused on how to look inside an operating energy storage system. While computational approaches have advanced over the last few decades, the development of experimental approaches has been very challenging, particularly for studying the light elements that are prevalent in energy storage materials.
An LLNL-led team developed a new X-ray adsorption spectroscopy capability that is tightly coupled with a modelling effort to provide key information about how the structure and bonding of graphitic carbon supercapacitor electrodes are affected by polarisation of the electrode - electrolyte interfaces during charging.
Graphitic supercapacitors are ideal model systems to probe interfacial phenomena because they are chemically relatively stable, extensively characterised experimentally and theoretically, and are interesting technologically. The team used its recently developed 3D nanographene (3D-NG) bulk electrode material as a model graphitic material.
“Our newly developed X-ray adsorption spectroscopy capability allowed us to detect the complex, electric-field induced changes in electronic structure that graphene-based supercapacitor electrodes undergo during operation. Analysis of these changes provided information on how the structure and bonding of the electrodes evolve during charging and discharging,” said Jonathan Lee, an LLNL scientist and corresponding author of a paper published in the journal Advanced Materials. “The integration of unique modelling capabilities for studying the charged electrode-electrolyte interface played a crucial role in our interpretation of the experimental data.”
Discovering that the electronic structure of graphitic carbon supercapacitor electrodes can be tailored by charge-induced electrode-electrolyte interactions opens a new window towards more efficient electrochemical energy storage systems. In addition, the experimental and modelling techniques developed during the research are readily applicable to other energy storage materials and technologies.
Other Livermore researchers include Michael Bagge-Hansen, Brandon Wood, Tadashi Ogitsu, Trevor Willey, Ich Tran, Arne Wittstock, Monika Biener, Matthew Merrill, Marcus Worsley, Theodore Baumann, Tony van Buuren and Jürgen Biener. The research was conducted in collaboration with scientists at additional institutions, including Minoru Otani from the Nanosystem Research Institute in Japan; David Prendergast from the Molecular Foundry; and Jinghua Guo and Cheng-Hao Chuang of the Advanced Light Source Division at Lawrence Berkeley National Laboratory.
The University of Phoenix Stadium in Glendale, AZ, has installed LED stadium lights from Ephesus...
Southern Cross Cable Network has appointed Anthony Briscoe as the new president and...
NECA has welcomed the decision of the ACCC to establish a taskforce to determine how best to...